NATURAL EXTRACTS AND THEIR EFFECT ON INHIBITING CORROSION PHENOMENA IN STEEL MATERIALS AND THEIR ENVIRONMENTAL IMPACT
DOI:
https://doi.org/10.31908/19098367.2927Keywords:
Corrosion, Natural extracts, Organic inhibitors, Environmental ImpactAbstract
Natural extracts are an inexhaustible source of organic compounds with a wide variety of applications such as, medicinal, pharmacological, environmental, among others; For this reason they have become the object of study in a large number of areas and specialties at industrial level. The present review shows the results of the use of extracts of natural origin with potential inhibition effect in corrosion processes on steel surfaces, given the amount of molecules that act synergistically in the process, such as flavonoids, coumarins and alkaloids, etc. which increase the prospects and research in the search for environmentally friendly alternatives and which contribute to the reduction of environmental impacts associated with increasing the water and carbon footprint, corrosion effect.
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A. Miralrio and A. E. Espinoza, “Plant Extracts as Green Corrosion Inhibitors for Different Metal Surfaces and Corrosive Media: A Review,” processes, vol. n.° 8, pp. 942, 2020, doi:https://doi.org/10.3390/pr8080942.
[2] S. Aourabi, M. Driouch, M. Sfaira, F. Mahjoubi, B. Hammouti, Chandrabham Verma, Eno E. Ebenso and L. Guo, “Phenolic Fraction of Ammi Visnaga Extract as Environmentally Friendly Antioxidant and Corrosion Inhibitor for Mild Steel in Acidic Medium,” Molecular Liquids, vol. 323, 2021, doi: https://doi.org/10.1016/j.molliq.2020.114950.
[3] L. T. Popoola, “Progress on Pharmaceutical Drugs, Plant Extracts and Ionic Liquids as Corrosion Inhibitors,” Heliyon, vol. 5, no. 2, 2019, doi: https://doi.org/10.1016/j.heliyon.2019.e01143.
[4] A. Zakeri, E. Bahmani and A. S. R. Aghdam, “Plant Extracts as Sustainable and Green Corrosion Inhibitors for Protection of Ferrous Metals in Corrosive Media: A mini review, Corrosion Communications, vol. 5, pp. 25–38, 2022, doi: https://doi.org/10.1016/j.corcom.2022.03.002.
[5] Z. Shang,, and J. Zhu, “Overview on Plant Extracts as Green Corrosion Inhibitors in the Oil and Gas Fields,” Journal of Materials Research and Technology, vol. 15, pp. 5078–5094, 2021, doi: https://doi.org/10.1016/j.jmrt.2021.10.095.
[6] I. Chung, Ramalingam Malathy, Rameshkumar Priyadharshini, Venkatesan Hemapriya, Seung-Hyum Kim, and Mayakrishnan Prabakaran, “Inhibition of Mild Steel Corrosion Using Magnolia Kobus Extract in Sulphuric Acid Medium,” Materials Today Communications, vol. 25, 2020, doi:https://doi.org/10.1016/j.mtcomm.2020.101687.
[7] S. Abdelaziz, M. Benamira, L. Messaadia, Y. Boughoues, H. Lahmar and A. Boudjerda, “Green Corrosion Inhibition of Mild Steel in HCl Medium Using Leaves Extract of Arbutus Unedo L. Plant: An Experimental and Computational Approach,” Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 619, 2021, doi: https://doi.org/10.1016/j.colsurfa.2021.126496.
[8] M. A.Bidi, M. Azadi and M. Rassouli, “An Enhancement on Corrosion Resistance of Low Carbon Steel by a Novel Bio-Inhibitor (Leech Extract) in the H2SO4 Solution,” Surfaces and Interfaces, vol. 24, 202, doi:https://doi.org/10.1016/j.surfin.2021.101159.
[9] A. Sedik, D. Lerari, A. Salci, S. Athmani, K. Bachari, I.H. Gecibesler and R. Solmaz, “Dardagan Fruit Extract as Eco-Friendly Corrosion Inhibitor for Mild Steel in 1 M HCl: Electrochemical and Surface Morphological Studies,” Journal of the Taiwan Institute of Chemical Engineers, vol. 107, pp. 189–200, 2020, doi:https://doi.org/10.1016/j.jtice.2019.12.006.
[10] L. Ghalib, H. J. Al Jaaf and H. A. Abdulghani, “Temperature Effect on the Efficiency of Eucalyptus Camaldulensis Leaves in the Acid Corrosion of Carbon Steel,” Materials Today: Proceedings, vol. 42, no 5, pp. 2475-2481, 2021, doi: https://doi.org/10.1016/j.matpr.2020.12.566.
[11] A. Dehghani and B. Ramezanzadeh, “Rosemary Extract Inhibitive Behavior Against Mild Steel Corrosion in Tempered 1 M HCl Media,” Industrial Crops and Products, vol. 193,pp. 116-183, 2023, doi: https://doi.org/10.1016/j.indcrop.2022.116183.
[12] S. Z. Salleh, A. H. Yusoff, S. K. Zakaria, M. A. Azhar Taib, A. A. Seman, M. N. Masri, M. Mohamad, S. Mamat, S. A. Sobri, A. Ali and P. T. Teo, “Plant Extracts as Green Corrosion Inhibitor for Ferrous Metal Alloys: A Review,” Journal of Cleaner Production, vol. 304, 2021, doi: https://doi.org/10.1016/j.jclepro.2021.127030.
[13] O.O. Ogunleye, A. O. Arinkoola, O. A. Eletta, Y. A. Osho, A. F. Morakinyo and J. O. Hamed, “Green Corrosion Inhibition and Adsorption Characteristics of Luffa Cylindrica Leaf Extract on Mild Steel in Hydrochloric Acid Environment,” Heliyon, vol. 6, no 1, 2020, doi: https://doi.org/10.1016/j.heliyon.2020.e03205.
[14] C. A. Coy, D. C. Gómez and F. A. Castiblanco, “Importancia medicinal del género Croton (euphorbiaceae),” Revista Cubana de Plantas Medicinales, vol. 21, no 2,pp. 234-247, 2016, doi:
[15] R. Haldhar, D. Prasad and A. Saxena, “Armoracia Rusticana as Sustainable and Eco-Friendly Corrosion Inhibitor for Mild Steel in 0.5M Sulphuric Acid: Experimental and Theoretical Investigations,” Journal of Environmental Chemical Engineering, vol. 6, no 4,pp 5230–5238, 2018, doi: https://doi-org.ezproxy.umng.edu.co/10.1016/j.jece.2018.08.025.
[16] R. K. Ahmed and S. Zhang,, “Atriplex leucoclada Extract: A Promising Eco-Friendly anticorrosive Agent For Copper in Aqueous Media,” Journal of Industrial & Engineering Chemistry, vol. 99,pp 334–343, 2021, doi: https://doi-org.ezproxy.umng.edu.co/10.1016/j.jiec.2021.04.042.
[17] S. Abbout, D. Chebabe, M. Zouarhi, M. Rehioui, Z. Lakbaibi and N. Hajjaji, “Ceratonia Siliqua L Seeds Extract as Eco-Friendly Corrosion Inhibitor for Carbon Steel in 1 M HCl: Characterization, Eectrochemical, Surface Analysis, and Theoretical Studies,” Molecular Structure, vol. 1240, 2021,doi: https://doi.org/10.1016/j.molstruc.2021.130611.
[18] V. Sivakumar, K. Velumani and S. Rameshkumar, “Colocid Dye - A Potential Corrosion Inhibitor for the Corrosion of Mild Steel in Acid Media,” Materials Research, vol. 21, no. 4, 2018, doi: https://doi.org/10.1590/1980-5373-MR-2017-0167.
[19] A. Ennouri, A. Lamiri and M. Essahli, “Corrosion Inhibition of Aluminium in Acidic Media by Different Extracts of Trigonellafoenum-graecum L Seeds,” Portugaliae Electrochimica Acta, vol. 35, no. 5,pp 279-295, 2017, doi: https://doi.org/10.4152/pea.201705279.
[20] Z.Zhang, D. Yan, X. Liu, W. Li, Z. Wang, Y. Wang, D. Song, T. Zhang, J. Liu and J. Wang, “Self-healing Nanocomposite Coatings Containing Organic-Inorganic Inhibitors Functionalized Dendritic Silica Nanocontainers for Synergistic Corrosion Protection of Carbon Steel,” Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 656, 2023, doi:https://doi.org/10.1016/j.colsurfa.2022.130430.
[21] A. Ehsani, M. G. Mahjani, M. Hosseini, R. Safari, M. Moshrefi and H. Mohammad Shiri, “Evaluation of Thymus Vulgaris Plant Extract as an Eco-Friendly Corrosion Inhibitor for Stainless steel 304 in Acidic Solution by Means of Electrochemical Impedance Spectroscopy, Electrochemical noise Analysis and Density Functional Theory,” Journal of Colloid and Interface Science, vol. 490,pp 444–451, 2017, doi: https://doi.org/10.1016/j.jcis.2016.11.048.
[22] N. Al Otaibi and H. H. Hammud, “Corrosion Inhibition Using Harmal Leaf Extract as an Eco-Friendly Corrosion Inhibitor,” Molecules, vol. 26, no. 22,pp 7024, 2021, doi: https://doi.org/10.3390/molecules26227024.
[23] K. Muthukumarasamy et al, “Adsorption and Corrosion Inhibition Performance of Tunbergia fragrans Extract on Mild Steel in Acid Medium,” Materials Today: Proceedings, vol. 33,pp 4054–4058, 2020 ,doi:https://doi.org/10.1016/j.matpr.2020.06.533.
[24] M. A. Deyab, Q. Mohsenb and L. Guo, “Aesculus hippocastanum seeds Extract as Eco-Friendly Corrosion Inhibitor for Desalination Plants: Experimental and Theoretical Studies,” Molecular Liquids, vol. 361, 2022 doi: https://doi.org/10.1016/j.molliq.2022.119594.
[25] A. G. Kalkhambkar, S. K. Rajappa, J. Manjanna and G. H. Malimath, “Saussurea obvallatta Leaves Extract as a Potential Eco-Friendly Corrosion Inhibitor for Mild Steel in 1 M HCl,” Inorganic Chemistry Communications, vol. 143,2022, doi: https://doi.org/10.1016/j.inoche.2022.109799
[26] Z. Sanaei, M. Ramezanzadeh, G. Bahlakeh and B. Ramezanzadeh, “Use of Rosa canina Fruit Extract as a Green Corrosion Inhibitor for mild steel in 1M HCl Solution: A Complementary Experimental, Molecular Dynamics and Quantum Mechanics Investigation,” Industrial and Engineering Chemistry, vol. 69,pp 18-31, 2019, doi: https://doi.org/10.1016/j.jiec.2018.09.013.
[27] Y. Fernine, R. Salim, N. Arrouse, R. Haldar, F. El Hajjaji, S. C. Kim, M. Ebn Touhami and M. Taleb, “Anti-corrosion Performance of Ocimum Basilicum Seed Extract as Environmental Friendly Inhibitors for Mild Steel in HCl Solution: Evaluations of Electrochemical, EDX, DFT and Monte Carlo, ” Molecular Liquids, vol. 355, 2022, doi:https://doi.org/10.1016/j.molliq.2022.118867.
[28] G. Villanueva, G. (2022). Corrosión del acero al carbón en medio ácido y su posible inhibición a partir de extractos obtenidos del sargazo. [Tésis de maestría] Universidad Autónoma del Estado de Morelos.
[29] B. Liao, Z. Luo, S. Wan and L. Chen, “Insight into the Anti-corrosion Performance of Acanthopanax Senticosus Leaf Extract as Eco-friendly Corrosion Inhibitor for Carbon Steel in Acidic Medium, ” .Journal of Industrial and Engineering Chemistry, vol. 117, pp. 238-246, 2023, doi:https://doi.org/10.1016/j.jiec.2022.10.010.
[30] M. Mehdipour, B. Ramezanzadeh and S. Arman, “Electrochemical Noise Investigation of Aloe Plant Extract as Green Inhibitor on the Corrosion of Stainless Steel in 1M H2SO4;, ” Journal of Industrial and Engineering Chemistry, vol. 21, pp. 318–327, 2015, doi: https://doi.org/10.1016/j.jiec.2014.02.041.
[31] N. Al Hasan, H. Alaradi, Z. A. Kadhim Al Mansor, A. H. Jabbar Al Shadood, “The Dual Effect of Stem Extract of Brahmi (Bacopamonnieri) and Henna as a Green Corrosion Inhibitor for Low Carbon Steel in 0.5 M NaOH Solution, ” Case Studies in Construction Materials, vol. 11, 2019, https://www.sciencedirect.com/science/article/pii/S2214509519304024
[32] E. Alibakhshi, M. Ramezanzadeh, G. Bahlakeh, B. Ramezanzadeh, Mahdavian and M. Motamedi,“Glycyrrhiza Glabra Leaves Extract as a Green Corrosion Inhibitor for Mild Steel in 1 M Hydrochloric Acid Solution: Experimental, Molecular Dynamics, Monte Carlo and Quantum Mechanics Study, ” Journal of Molecular Liquids, vol. 255, pp. 185–198, 2018, doi: https://www.sciencedirect.com/science/article/abs/pii/S0167732217359949.
[33] J. Bhawsar, P. Jain and P. Jain, “Experimental and Computational Studies of Nicotiana Tabacum Leaves Extract as Green Corrosion Inhibitor for Mild Steel in Acidic Medium, ” Alexandria Engineering Journal, vol. 54, no. 3, pp. 769–775, 2015, doi:https://doi-org.ezproxy.umng.edu.co/10.1016/j.aej.2015.03.02.
[34] K. Azzaoui, E. Mejdoubi, S. Jodeh, A. Lamhamdi, E. Rodríguez-Castellón, M. Algarra, A. Zarrouk, A. Errich, R. Salghi and H. Lgaz, “Eco-friendly Green Inhibitor Gum Arabic (GA) for the Corrosion Control of Mild Steel in Hydrochloric Acid Medium, ” Corrosion Science, vol. 129, pp. 70–81, 2017, doi: https://www.sciencedirect.com/science/article/abs/pii/S0010938X17309824 .
[35] P. Divya, S. Subhashini, A. Prithiba and R. Rajalaksmi, “Tithonia Diversifolia Flower Extract as Green Corrosion Inhibitor for Mild Steel in Acid Medium, ” Materials Today Proceedings, vol. 18, no. 4, pp. 1581–1591, 2019, doi: https://www.sciencedirect.com/science/article/abs/pii/S2214785319310983 .
[36] A. El Bribri et al., “The Use of Euphorbia Falcata Extract as Eco-friendly Corrosion Inhibitor of Carbon Steel in HCl Solution, ” Materials Chemistry and Physics, vol. 141, no. 1, pp. 240–247, 2013, doi: https://doi-org.ezproxy.umng.edu.co/10.1016/j.matchemphys.2013.05.006.
[37] H. Hassan, A. Khadom and N. Kurshed, “Citrus Aurantium Leaves Extracts as a Sustainable Corrosion Inhibitor of Mild Steel in Sulfuric Acid, South African, ” Journal of Chemical Engineering, vol. 22, pp. 1-5, 2016, doi:https://doi.org/10.1016/j.sajce.2016.07.002.
[38] R. Fdil, M. Tourabi, S. Derhali, A. Mouzdahir, K. Sraidi, C. Jama, A. Zarrouk and F. Bentiss, “Evaluation of Alkaloids Extract of Retama Monosperma (L.) Boiss. Stems as a Green Corrosion Inhibitor for Carbon Steel in Pickling Acidic Medium by Means of Gravimetric, AC Impedance and Surface Studies, ” Journal of Materials and Environmental Sciences, vol. 9, pp. 358-369, 2018, doi: https://lilloa.univ-lille.fr/handle/20.500.12210/9233 .
[39] Y. Fang, B. Suganthan and R. Ramasamy, “Electrochemical Characterization of Aromatic Corrosion Inhibitors from Plant Extracts, ” Journal of Electroanalytical Chemistry, vol. 840, pp. 74–83, 2019, doi: https://doi.org/10.1016/j.jelechem.2019.03.052.
[40] N. Abba, R. Idouhli, A. T. Ilagouma, A. Abouelfida, M. Kadhiri and A. Romane, “Use of Endostemon Tereticaulis (Pear.) M.Ashby and Hyptis Spicigera Lam Plant Extracts as Corrosion Green Inhibitors for Mild Steel in 1M HCl: Electrochemical and Surface Morphological Studies, ” Protection of Metals & Physical Chemistry of Surfaces, vol. 57, no. 3, pp. 619–633, 2021, doi: https://link.springer.com/article/10.1134/S2070205121030035.
[41] M. Prabakaran, S. Kim, A. Sasireka, K. Kalaiselvi and I. Chung, “Polygonatum Odaratum Extract as an Eco-friendly Inhibitor for Aluminum Corrosion in Acidic Medium, ” Journal of Adhesion Science & Technology, vol. 32, no. 18, pp. 2054–2069, 2018, doi: https://www.tandfonline.com/doi/full/10.1080/01694243.2018.1462947
[42] Z. Zhou, X. Min, S. Wan, J. Liu, B. Liao and Z. Guo, “A Novel Green Corrosion Inhibitor Extracted from Waste Feverfew Root for Carbon Steel in H2SO4 Solution, ” Results in Engineering, vol. 17, 2023, doi:10.1016/j.rineng.2023.100971
[43] P. Álvarez, M. Fiori-Bimbi, A. Neske, S. A. Brandán and A. Gervasi,, “Rollinia Occidentalis Extract as Green Corrosion Inhibitor for Carbon Steel in HCl Solution, ” Journal of Industrial and Engineering Chemistry, vol. 58, pp. 92-99, 2018, doi:10.1016/j.jiec.2017.09.012
[44] A. ElShami, S. Bonnet, M. Hussein Makhlouf, A. Khelidj and N. Leklou, “Novel Green Plants Extract as Corrosion Inhibiting Coating for Steel Embedded in Concrete, ” Pigment & Resin Technology, vol. 49, no. 6, pp. 501–514, 2020, doi: https://www.emerald.com/insight/content/doi/10.1108/PRT-09-2019-0078/full/html
[45] R. Anitha, Unnisa N., Basha C., V. Hemapriya, S. Mohana Soopan, S. Chitra, I. Chung, S. Kim and P. Mayakrishnan “Anti-corrosive Potential of Cyperus Rotundus as a Viable Corrosion Inhibitor for Mild Steel in Sulphuric Acid, ” Pigment & Resin Technology, vol. 49, no. 4, pp. 295–304, 2020, doi: https://www.ingentaconnect.com/content/mcb/129/2020/00000049/00000004/art00006
[46] M. Prabakaran, S. Kim, V. Hemapriya and I. Chung, “Tragia Plukenetii Extract as an Eco-friendly Inhibitor for Mild Steel Corrosion in HCl 1 M Acidic Medium, ” Research on Chemical Intermediates, vol. 42, no. 4, pp. 3703–3719, 2016, doi: https://openurl.ebsco.com/EPDB%3Agcd%3A4%3A29430644/detailv2?sid=ebsco%3Aocu%3Arecord&id=ebsco%3Adoi%3A10.1007%2Fs11164-015-2240-x&bquery=AU%20Kim%2C%20Seung-Hyun&page=1.
[47] F. Suedile, F. Robert, C. Roos and M. Lebrini, “Corrosion Inhibition of Zinc by Mansoa Alliacea Plant Extract in Sodium Chloride Media: Extraction, Characterization and Electrochemical Studies, ” Electrochimica Acta, vol. 133, pp. 631–638, 2014, doi: https://www.sciencedirect.com/science/article/abs/pii/S0013468613025103.
[48] S. Wan, H. Wei, R. Quan, Z. Luo, H. Wang, B. Liao and X. Guo, “Soybean Extract Firstly Used as a Green Corrosion Inhibitor with High Efficacy and Yield for Carbon Steel in Acidic Medium, ” Industrial Crops and Products, vol. 187, 2022, doi:10.1016/j.indcrop.2022.115354
[49] Q. Xiang and J. He, “Combining Theoretical and Experimental Research to Understand the Anti Corrosive Nature of Citrus Reticulata Leaf Extract, ” Molecular Liquids Journal,, vol. 325, 2021, doi: https://doi-org.ezproxy.umng.edu.co/10.1016/j.molliq.2020.115218
[50] D. Pineda, E. Restrepo, P. Arango, B. Segura and C. Acosta, “Innovative Method for Coating of Natural Corrosion Inhibitor Based on Artemisia Vulgaris, ” Materials, vol. 14, no. 9, 2021, doi: 10.3390/ma14092234
[51] D. Pedroza, M. Villalobos-Vazquez, P. Meza-Castellar and I. Paz-Astudillo, “Evaluation of Cocoa (Theobroma Cacao L.) Shell Extracts as Corrosion Inhibitors in Carbon Steel, ” Technology Science Future, vol .6, n. 3, pp. 147-156, 2016, doi: http://www.scielo.org.co/scielo.php?pid=S0122-53832016000100009&script=sci_arttext&tlng=en
[52] F. Kaya, R. Solmaz, and I. H. Geçibesler, “The Use of Methanol Extract of Rheum Ribes (Işgın) Flower as a Natural and Promising Corrosion Inhibitor for Mild Steel Protection in 1 M HCl Solution,” Journal of Industrial and Engineering Chemistry, vol. 122, pp. 102-117, 2023, doi: https://doi.org/10.1016/j.jiec.2023.02.013
[53] E. A. Şahin, Y. Dursun, I. Gecibesler and R. Solmaz, “Adsorption and Corrosion Inhibition Ability of Avocado Seed (Persea americana) Extract for Copper Corrosion in 0.5 M H2SO4 Solution,” Inorganic Chemistry Communications, vol. 167, 2024, doi: https://doi.org/10.1016/j.inoche.2024.112751
[54] H. Liem, T. D. Manh, L. T. Nguyen, D T. Vu, D. T. Vu, K. D. Nguyen and K. L. Ngo, “Syzygium Polyanthum (Wight) Walp. Leaf Extract as a Sustainable Corrosion Inhibitor for Carbon Steel in Hydrochloric Acidic Environment,” Journal of Industrial and Engineering Chemistry, vol. In press, Journal Pre-proof, 2024, doi: https://doi.org/10.1016/j.jiec.2024.08.054
[55] H. S. Kusuma, G. S. Danera, A. D. Maulana, M. Rahmasari, R. A. Nida, A. N. Amenaghawon, H. Darmokoesoemo and A. Zarrouk, “Effect of Spinach (Spinacia oleracea) leaf Extract on the Aluminum (Al) as a Green Corrosion Inhibitor in HCl Medium,” Hybrid Advances, vol. 7, 2024, doi: https://doi.org/10.1016/j.hybadv.2024.100283
[56] T. Rajachandrasekar, I. Muthuvel, K. Kavitha, S.R. Anishia, S. Sasikruba and S. Sujatha, “An Investigation Into the Corrosion Inhibition Mechanisms of Mild Steel Using Aqueous Extract derived from Aerva lanata Leaf in an Acidic Environment,” Materials today: Proceedings, In press, Corrected Proof, 2024, doi: https://doi.org/10.1016/j.matpr.2024.04.024
[57] S. N. Houda, B. Amel, and F. Malika, “Trifolium Repens Extracts as a Green Corrosion Inhibitor for Carbon Steel in a 3.5% NaCl Solution,” Journal of the Taiwan Institute of Chemical Engineers, vol. 165, 2024, doi: https://doi.org/10.1016/j.jtice.2024.105771
[58] M. M. . Nageeb, G. A. Gaber, A. Ahmed and A. Fouda, “Application of Lentil Seed Extract as an Inhibitor to Assess the Corrosion Properties of Copper–nickel Alloys in a NaCl Environment,” RSC Advances, vol. 14, no. 38, pp. 28044-28057, 2024, doi: https://doi.org/10.1039/d4ra04758c
[59] S. Mandal, S. Das, R. Gupta and K. Mondal, “Excellent Corrosion Inhibition Efficiency of Catharanthus Roseus (Nayantara or Sadabahar) Leaf Aqueous Extract on Mild Steel in Chloride-Contaminated Solutions at Different pH,” Sustainable Materials and Technologies, vol. 41, 2024, doi: https://doi.org/10.1016/j.susmat.2024.e01058
[60] R. A. Saxena, J. Kaur, E. Berdimurodov and D. K. Verma, “Synergistic Mixture of the Dactyloctenium aegyptium Extract and KI as an Environment Friendly and Highly Efficient Corrosion Inhibitor for Steel in 0.5 M HCl,” Journal of the Indian Chemical Society, vol. 101, no. 10, 2024, doi: https://doi.org/10.1016/j.jics.2024.101317
[61] F. E. Abeng. B. I. Ita, M. E. Ikpi, V. I. Chukwuike, A. I. Ikeuba, M. M. Edim, M. A. Chidiebere, A. Thakur and V. C. Anadebe,, “Millettia Aboensis Leaves Extract as Eco-Friendly Corrosion Inhibitor for Mild Steel in Acidizing Solution: From Experimental to Molecular Level Prediction,” Results in Engineering, vol. 24, 2024, doi: https://doi.org/10.1016/j.rineng.2024.102950
[62] M. T. Muhammad, M. H. Hussin, M. A. Abu Bakar, T. S. Hamidon, S. S. Azahar, K. Awang, M. Lituadon, M. N. Azmi, “Corrosion Inhibitive Performance of Kopsia teoi Extracts Towards Mild Steel in 0.5 M HCl Solution, “ Materials Chemistry and Physics, vol. 322, no. 1, 2024, doi: https://doi.org/10.1016/j.matchemphys.2024.129584
[63] A.Dutta, J. Kaur, and A. Saxena, “Boosting the Corrosion Inhibition Efficiency of the Clerodendrum Serratum Extract for Steel in the Presence of KCl,” Chemical Data Collections, vol. 52, 2024, doi: https://doi.org/10.1016/j.cdc.2024.101148
[64] B. A. Abd-El-Nabey, M.E. Mohamed, A.M. Helmy, H. Elnagar and A.M. Abdel-Gaber, “Eco-friendly Corrosion Inhibition of Steel in Acid Pickling Using Prunus domestica Seeds and Okra Stems Extracts,” International Journal of Electrochemical Science. vol. 19, no. 8, 2024, doi: https://doi.org/10.1016/j.ijoes.2024.100695
[65] Q. Wang, X. Zhou, X. Sun, Q. Zhang, R. Wang, J. Zhao, R. Aslam, Y. Sun, Z. Yan and X. Li, “Seaweed Extract as Green Corrosion Inhibitor for Carbon Steel in Hydrochloric Acid Solution,” Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 700, no. 5, 2024, doi: https://doi.org/10.1016/j.colsurfa.2024.134751
[66] V. M. Paiva, R. Silva, K. C. de Santana de Lima, S. Oliveira, J. Araujo, B. Archanjo, A. F. Valle and E. D’Elia, “Novel Eco-friendly Green Inhibitor of Corrosion Based on Acerola (Malpighia glabra) Waste Aqueous Extract for Mild Steel in 1 mol L–1 HCl Solution,” Surfaces and Interfaces, vol. 47, 2024, doi: https://doi.org/10.1016/j.surfin.2024.104187
[67] X. An, J. Dai, S. Wang and W. Zou, “Exploring Ginkgo Biloba Extract's Green Corrosion Inhibition Effects on Q235 Steel in H2SO4 Environments,” International Journal of Electrochemical Science, vol. 19, no. 8, 2024, doi: https://doi.org/10.1016/j.ijoes.2024.100677
[68] A.Thakur, O. Dagdag, A. Berisha, E. E. Ebenso, A. Kumar, S. Sharma, R. Ganjoo and H. Asaad, “Mechanistic Insights into the Corrosion Inhibition of Mild Steel by Eco-benign Asphodelus Tenuifolius Aerial Extract in Acidic Environment: Electrochemical and Computational Analysis,” Surface and Coatings Technology, vol. 430, no. 30, 2024, doi. https://doi.org/10.1016/j.surfcoat.2024.130568
[69] T. Tran, N. Hoaai Vu, T. Tran, S. Jo, T. Huynh, T. Nguyen, C. Panaitescu, H. T. Nguyen, V. Nguyen and N. Nguyeng Dang, “Precise Major Compounds in Barringtonia Acutangula Flower – Water Extract for Mitigating Carbon Steel Corrosion,” Journal of the Taiwan Institute of Chemical Engineers, vol. 155, 2024, doi: https://doi.org/10.1016/j.jtice.2023.105251
[70] Z. Jia, B. Lin, T. Duan, H. Lin, G. Zhang, X. Zhou and Y. Xu, “Zea Mays Bracts Extract as an Eco-friendly Corrosion Inhibitor for Steel in HCl Pickling Solution: Experimental and simulation studies,” Arabian Journal of Chemistry, vol. 17, pp 105895, 2024, doi: 10.1016/J.ARABJC.2024.105895
[71] M. Ukasha, J. Hernandez, S. Umoren, M. Sahban and R. Lim, “Investigations of Corrosion Inhibition of Ethanolic Extract of Dillenia Suffruticosa Leaves as a Green Corrosion Inhibitor of Mild steel in Hydrochloric Acid Medium,” Corrosion Communications, vol. 15, pp 52-62, 2024, doi: https://doi.org/10.1016/j.corcom.2023.10.005
[72] H. abbod, and A. Khadom, “Okra Leaves Extract as Green Corrosion Inhibitor for Steel in Sulfuric Acid: Gravimetric, Electrochemical, and Surface Morphological Investigations,” Results in Chemistry, vol. 8, pp 101566, 2024, doi: https://doi.org/10.1016/j.rechem.2024.101566
[73] B. Ahmed, C. Abdelkarim, E. Omar, B. M’hammed, B. Lahcen and S. Rachid, “Waste Extract as an Efficient Organic compound for Corrosion Inhibition of Carbon Steel (C38) in HCl Solution,” Sustainable Chemistry and Pharmacy, vol. 27, pp 101677, 2024, doi: https://doi.org/10.1016/j.scp.2022.100677
[74] A. Sina, R. Reza, and R. Bahram., “Fabrication and Characterization of Zinc Acetylacetonate/Urtica Dioica Leaves Extract Complex as an effective organic/inorganic hybrid corrosion inhibitive pigment for mild steel protection in chloride solution,” Applied Surface Science, vol. 457, pp 487-496, 2024, doi: https://doi.org/10.1016/j.apsusc.2018.06.190
[75] Z. Farah, H. Sherwyn, and H. Hussin., “Applicability of Winged Bean Extracts as Organic orrosion Inhibitors for Reinforced Steel in 0.5 M HCl Electrolyte,” Journal of the Indian Chemical Society, vol. 27, pp 100329, 2022, doi: https://doi.org/10.1016/j.jics.2021.100329
[76] M. Boudaliaa, A. Guenbour, A. Bellaouchou, A. Laqhalli, M. Mousanddak, A. Hakiki, B. Hammouti and E. Ebenso, “Corrosion Inhibition of Organic Oil Extract of Leaves Of Lanvandula Stoekas on Stainless Steel in Concentrated Phosphoric Acid Solution,” International Journal of Electrochemical Science, vol. 8, pp 7414-7424, 2022, doi: https://doi.org/10.1016/S1452-3981(23)14856-5
[77] P. Li, Z. Shao, W. Fu, W. Ma, K. Yang, H. Zhou and M. Gao, “Enhancing Corrosion Resistance of Magnesium Alloys via Combining Green Chicory Extracts and Metal Cations as Organic-Inorganic Composite Inhibitor,” Corrosion Communications, vol. 9, pp 44-56, 2024, doi: https://doi.org/10.1016/j.corcom.2022.06.002
[78] J. Nogueira, V. Paiva, A. Monteiro, G. Almeida, R. Da Silva, B. Soares, S. Massafra, J. Rodrigues, A. Ferreira, T. Das Chagas and E. D’Elia, Versatility of Juçara (Euterpe edulis) extracts as corrosion inhibitors of mild steel in different environments: 1 mol L−1 HCl and CO2-saturated formation water, Journal of Materials Research and Technology, vol. 32, pp1159-1172, 2024, doi: https://doi.org/10.1016/j.jmrt.2024.07.206
[79] P. Van, N. Tu Hoang, T. Dihn, L. Dung, N. Si Hoaui, S. V. Prabhakar, C. Panaitescu, T. Pham and N. Nguyen, “Enhancing Corrosion Resistance of Mild Steel in Hydrochloric acid with Chiquita Banana Sap Extract,” RSC Advances, vol. 14, pp 14263-14277, 2024, doi: https://doi.org/10.1039/d4ra00132j
[80] M. Darweesh, S. M. Emam, A. Wahba, M. I. Ayad, M. El-Nahass, Am Abd-Elhamied and W. A. Hammad, “Onion Peel Extract/Copper Oxide Nanoparticles as Corrosion Inhibitors for Carbon Steel in Hydrochloric Acid: Extraction, Characterization, Electrochemical Study, and Theoretical Explorations,” Results in Chemistry, vol. 9, pp 101126, 2024, doi: https://doi.org/10.1016/j.rechem.2024.101626
[81] D. Pengfei, Y. Huifang, D Shuduan and L. Xianghong, “Synergistic Inhibition of Mikania Micrantha Extract with Iodide Ion on the Corrosion of Cold Rolled Steel in Trichloroacetic Acid Medium,” Journal of Industrial and Engineering Chemistry, vol. 139, pp 358-377, 2024, doi: https://doi.org/10.1016/j.jiec.2024.05.014
[82] L. Ran, D. Shuduan, Q. Yujie, X. Dake, D. Guanben, S. Dandan and L. Xianghong, “Sunflower Stalk Extract as a Novel Green Inhibitor on Aluminium Corrosion in HCl Solution,”Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 687, pp 133358, 2024, doi: https://doi.org/10.1016/j.colsurfa.2024.133358
[83] P. Bishnu, P. Dipak, P. Naresh, P. Deval, D. Madhusudan and B. Hari, “Methanol Extract of Murraya Koenigii Stem as Green Inhibitor for Mild Steel Corrosion in 1 M HCl solution,”Results in Surfaces and Interfaces, vol. 16, pp 100245, 2024, doi: https://doi.org/10.1016/j.rsurfi.2024.100245
[84] A. El Ouaddari, R. Kellal, Z. Ait El Caid, R. Albarakati, N. Wazzan, O. S. Al-Quarashi, Z. Safi, S. Iben Moussa, A. El Amrani, M. Zertoubi and D. Benmessauoud “Insight Into Anti-Corrosion Behavior of Cladanthus Mixtus (L.) Flower Extracts as a Biodegradable Inhibitor for Carbon Steel in Acid Medium: Experimental and Theoretical Studies,” Materials Chemistry and Physics, vol. 326, pp 129827, 2024, doi: https://doi.org/10.1016/j.matchemphys.2024.129827
[85] A. Siti, B. Pandian, I. Mohamad, A Khalijah, Z. Mohd, H. Tuan and H. Hazwan, “Extraction of flavonoids from Butterfly blue pea (Clitoria ternatea) flower as Carbon Steel Corrosion Inhibitor in CO2 Environment: Experimental and Theoretical Approaches,” Journal of Molecular Liquids, vol. 396, pp 124056, 2024, doi: https://doi.org/10.1016/j.molliq.2024.124056
[86] S. Adhikary, and N. Dasgupta, “Role of Secondary Metabolites in Plant Homeostasis During Biotic Stress,” Biocatalysis and Agricultural Biotechnology, vol. 50, no. 102712, 2023, doi:10.1016/j.bcab.2023.102712
[87] B. Li, J. Wang, Z. Cheng, B. Song, C. Shu, Y. Chen, W. Chen, S. Yang, Y. Yang and J. Tian, “Flavonoids Mitigation of Typical Food Thermal Processing Contaminants: Potential Mechanisms and Analytical Strategies, ” Food Chemistry, vol. 416, no. 135793, 2021, doi:10.1016/j.foodchem.2023.135793
[88] S. Sirin, S. Dolanbay and B Aslim, “Role of Plant Derived Alkaloids as Antioxidant Agents for Neurodegenerative Diseases,” Health Sciences Review, vol. 6, 2022, doi: 100071. doi:10.1016/j.hsr.2022.100071.
[89] C. Santos, S, Machado, E Matos Sales, E. Da Silva Velozo, E. Porto Dos Santos, G. Baptista, F. Azeredo, T. Fraga Barros and R Biegelmayer, “Coumarins from Rutaceae: Chemical Diversity and Biological Activities”, Fitoterapia, vol. 168, no. 105489, 2023, doi:10.1016/j.fitote.2023.105489
[90] N. Hossain, M. Islam, M. Chowdhury, “Advances of Plant-Extracted inhibitors in Metal Corrosion Reduction – Future Prospects and Challenges,” Results in Chemistry, vol. 5, 2023, doi:10.1016/j.rechem.2023.100883.
[91] C. Verma, M. Alfantazi and Y. Kyong, “Are Extracts Really Green Substitutes for Traditional Toxic Corrosion Inhibitors? Challenges Beyond Origin and Availability, ” Sustainable Chemistry and Pharmacy, vol. 31, 2023, doi: https://doi.org/10.1016/j.scp.2022.100943
[92] F. Abd El Aziz, M. Ahmed, A, Mohammed, E. Ahmed and A. Mohamed S.,“Verbena officinalis (VO) leaf extract as an anti-corrosion inhibitor for carbon steel in acidic environment,” Sci Rep, vol 14, pp 16112, 2024, doi: https://doi.org/10.1038/s41598-024-65266-z
[93] A. Liberati, D, Altman, J. Tezlaff, C. Mulrow, P. Gotzche, H. Loannidis, M. Clarke, P. J. Devereaux, J. Kleijnen and D. Moher,“The PRISMA statement for reporting systematic reviews and meta-analyses of studies that evaluate health care interventions: explanation and elaboration,” J Clin Epidemiol, vol. 62, no. 10, pp. e1–e34, Oct. 2009, doi: 10.1016/J.JCLINEPI.2009.06.006
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